Search for: All records

Abstract. Indole (ind) is a nitrogen-containing heterocyclic volatile organic compound commonly emitted from animal husbandry and from different plants like maize with global emissions of 0.1 Tg yr−1. The chemical composition and optical properties of indole secondary organic aerosol (SOA) and brown carbon (BrC) are still not well understood. To address this, environmental chamber experiments were conducted to investigate the oxidation of indole at atmospherically relevant concentrations of selected oxidants (OH radicals and O3) with or without NO2. In the presence of NO2, the SOA yields decreased by more than a factor of 2, but the mass absorption coefficient at 365 nm (MAC365) of ind-SOA was 4.3 ± 0.4 m2 g−1, which was 5 times higher than that in experiments without NO2. In the presence of NO2, C8H6N2O2 (identified as 3-nitroindole) contributed 76 % to all organic compounds detected by a chemical ionization mass spectrometer, contributing ∼ 50 % of the light absorption at 365 nm (Abs365). In the absence of NO2, the dominating chromophore was C8H7O3N, contributing to 20 %–30 % of Abs365. Indole contributes substantially to the formation of secondary BrC and its potential impact on the atmospheric radiative transfer is further enhanced in the presence of NO2, as it significantly increases the specific light absorption of ind-SOA by facilitating the formation of 3-nitroindole. This work provides new insights into an important process of brown carbon formation by interaction of two pollutants, NO2 and indole, mainly emitted by anthropogenic activities.

 

The Pacific–North American (PNA) teleconnection pattern is one of the prominent atmospheric circulation modes in the extratropical Northern Hemisphere, and its seasonal to interannual predictability is suggested to originate from El Niño–Southern Oscillation (ENSO). Intriguingly, the PNA teleconnection pattern exhibits variance at near-annual frequencies, which is related to a rapid phase reversal of the PNA pattern during ENSO years, whereas the ENSO sea surface temperature (SST) anomalies in the tropical Pacific are evolving much slower in time. This distinct seasonal feature of the PNA pattern can be explained by an amplitude modulation of the interannual ENSO signal by the annual cycle (i.e., the ENSO combination mode). The ENSO-related seasonal phase transition of the PNA pattern is reproduced well in an atmospheric general circulation model when both the background SST annual cycle and ENSO SST anomalies are prescribed. In contrast, this characteristic seasonal evolution of the PNA pattern is absent when the tropical Pacific background SST annual cycle is not considered in the modeling experiments. The background SST annual cycle in the tropical Pacific modulates the ENSO-associated tropical Pacific convection response, leading to a rapid enhancement of convection anomalies in winter. The enhanced convection results in a fast establishment of the large-scale PNA teleconnection during ENSO years. The dynamics of this ENSO–annual cycle interaction fills an important gap in our understanding of the seasonally modulated PNA teleconnection pattern during ENSO years. 

Abstract Current climate models have relatively high skills in predicting El Niño–Southern Oscillation (ENSO) phase (i.e., El Niño, neutral, and La Niña), once leaping over the spring predictability barrier. However, it is still a big challenge to realistically forecast the ENSO amplitude, for instance, whether a predicted event will be strong, moderate, or weak. Here we demonstrate that the accumulated westerly wind events (WWEs)/easterly wind surges (EWSs) and oceanic recharged/discharged states are both of importance in accurate ENSO amplitude forecasts. El Niño and La Niña events exhibit asymmetric temporal and spatial features in the atmospheric and oceanic preconditions. El Niño amplitude at the peak season is closely associated with the accumulated WWEs over the eastern equatorial Pacific from the previous December to May and the recharged state in the western equatorial Pacific during February. In contrast, the amplitude of La Niña events is sensitive to the accumulated EWSs over the equatorial western Pacific from the previous November to April and the discharged state extending from the equatorial western to central Pacific during February. Considering these asymmetric atmospheric and oceanic preconditions of El Niño and La Niña cases, a statistical model is established to accurately forecast the ENSO amplitude at its mature phase during 1982–2018, which is validated to be robust based on a 1-yr cross-validation and independent sample tests. The feasibility and the limitation of the established statistical model are also discussed by examining its practical utility. 

Abstract The El Niño-Southern Oscillation (ENSO), the primary driver of year-to-year global climate variability, is known to influence the North Tropical Atlantic (NTA) sea surface temperature (SST), especially during boreal spring season. Focusing on statistical lead-lag relationships, previous studies have proposed that interannual NTA SST variability can also feed back on ENSO in a predictable manner. However, these studies did not properly account for ENSO’s autocorrelation and the fact that the SST in the Atlantic and Pacific, as well as their interaction are seasonally modulated. This can lead to misinterpretations of causality and the spurious identification of Atlantic precursors for ENSO. Revisiting this issue under consideration of seasonality, time-varying ENSO frequency, and greenhouse warming, we demonstrate that the cross-correlation characteristics between NTA SST and ENSO, are consistent with a one-way Pacific to Atlantic forcing, even though the interpretation of lead-lag relationships may suggest otherwise.